Minimally Invasive BioChimney Method of Postrepair Mitral Stenosis

And the Proteobacteria became ascendant at the perchlorate concentration of 20 mg L-1. The functional populations for perchlorate reduction were successfully enriched including Nitrosomonas (30%), Thermomonas (9%), Comamonas (8%) and Hydrogenophaga (3%). Meanwhile, the proportion of functional population in biofilm linked to perchlorate concentration. With the increase of influent perchlorate concentration, the perchlorate-reducing bacteria (PRB) were enriched successfully and became ascendant.Propylbenzenes (PBZs) and trimethylbenzenes (TMBs) are aromatic hydrocarbon compounds widely used in many industries with potential release to different environments. The fate and aquatic effects of these compounds in the environment were evaluated. Evidence suggests that PBZs and TMBs will rapidly volatilise from water and bioaccumulate in aquatic organisms. Under both aerobic and anaerobic conditions, these compounds are readily biodegradable, whereby 1,2,3-TMB is more stable than the others. In air, all five compounds have atmospheric photo-oxidation half-lives ranging from 0.31 to 1.55 d. The toxicity data collectively show that PBZs, 1,2,4- and 1,3,5-TMB pose high acute toxicity effects on aquatic organisms. Furthermore, freshwater species are more sensitive to these compounds than marine species. There is not much data on the occurrence of PZBs and TMBs in the aquatic environment. This review presents the current state of knowledge on the fate of PBZs and TMBs. Moreover, the acute and joint toxicity of these compounds to different aquatic organisms, especially in marine organisms, warrants further investigation.In order to facilitate recovery and enhance phosphate adsorption capacity of lanthanum (La)-based materials, magnetic Fe3O4@MgAl-LDH@La(OH)3 (MMAL) composites with a hierarchical core-shell structure were synthesized. In the preparation process, citric acid played a vital role in the morphology control of La(OH)3, deciding the La content and phosphate adsorption capacity of materials. MMAL composites with a citric acid-to-La molar ratio of 0.375 (MMAL-0.375) exhibited a high adsorption capacity of 66.5 mg P/g, fast adsorption kinetics of 30 min, widely applicable pH range of 4.0-10.0, outstanding selective adsorption performance, and superior reusability in batch adsorption experiments. Moreover, the phosphate in the desorption solution could be concentrated by repeated use of desorption solution and recovered by using CaCl2. When the obtained composites were used for the sedimentary phosphorus sequestration and recovery, the results showed that the addition of MMAL-0.375 effectively reduced the concentration of soluble reactive phosphorus (SRP) in the overlying water. selleck Accompanied by an evident increase in HCl-extractable phosphorus (HCl-P), mobile phosphorus (Pmob) in sediments was effectively reduced. This work indicates that the MMAL-0.375 composites can serve as an effective tool for the removal of phosphate from wastewater and the control of sedimentary phosphorus.Lonar Lake, India; a hypersaline and hyperalkaline extremophilic ecosystem having a unique microbial population has been rarely explored for bioremediation aspects. MinION-based shotgun sequencing was used to comprehensively compare the microbial diversity and functional potential of xenobiotic degradation pathways with seasonal changes. Proteobacteria and Firmicutes were prevalent bacterial phyla in the pre-monsoon and post-monsoon samples. Functional analysis from SEED-subsystem and KEGG database revealed 28 subsystems and 18 metabolic pathways for the metabolism of aromatic compounds and xenobiotic biodegradation respectively. Occurrence of N-phenyl alkanoic, benzoate, biphenyl, chloroaromatic, naphthalene, and phenol degradation genes depicted varied abundance in the pre-monsoon and post-monsoon samples. Further, KEGG analysis indicated nitrotoluene degradation pathway (ko00633) abundant in post-monsoon samples, and the benzoate degradation pathway (ko00362) predominant in 19LN4S (pre-monsoon) than 18LN7S (post-monsoon) samples. The abundant genes for benzoate degradation were pcaI 3-oxoadipate CoA-transferase, alpha subunit, pcaH protocatechuate 3,4-dioxygenase, beta subunit, and pcaB 3-carboxy-cis, cis-muconate cycloisomerase, and 4-oxalocrotonate tautomerase. This metagenomic study provides a unique blueprint of hitherto unexplored xenobiotic biodegradation genes/pathways in terms of seasonal variations in the Lonar Lake, and warrants active exploitation of microbes for bioremediation purposes.Hexachlorocyclohexane isomers (HCH) are persistent organic pollutants which cause serious environmental pollution. Phytoextraction is one of the strategies of phytoremediation, which was considered as a promising method for the clean-up of HCH contaminated field sites. To understand the uptake and translocation mechanisms of HCH in soil-plant system, the uptake of HCH from the gas phase was investigated in a tracer experiment with 13C-labeled α-HCH. The results provide new insights on the uptake mechanism of HCH and allow the elucidation of transport pathways of POPs from the leaves to the rhizosphere. A higher dissipation of α-HCH in planted set-ups versus unplanted controls indicated next to intensive biodegradation in the rhizosphere the removal of HCH by root uptake, accumulation and possible transformation within plants. Analyzing the carbon isotopic composition (δ13C) of α-HCH in the soil of unplanted controls revealed a change of 15.8-28.6‰ compared to the initial δ13C value, indicating that a soil gas phase transportation of α-HCH occurred. Additionally, higher δ13C values of α-HCH were observed in bulk and rhizosphere soil in non-labeled treatments compared to unplanted controls, revealing the uptake of α-HCH from the gas phase by the leaves and the further translocation to the roots and finally release to the rhizosphere. This uptake by the leaves and the subsequent translocation of α-HCH within the plant is further indicated by the observed variations of the δ13C value of α-HCH in different plant tissues at different growth stages. The uptake and translocation pathways of α-HCH from the gas phase need to be considered in phytoremediation.